Charging LiFePO4 Batteries with Solar Charge Controllers
Most standard solar charge controllers can effectively charge lithium-ion batteries, such as LiFePO4 (Lithium Iron Phosphate) batteries, because the required voltages are similar to those for AGM (Absorbent Glass Mat) batteries.
Battery Management System (BMS) in LiFePO4 batteries ensures that the cells receive the correct voltage, preventing overcharging or over-discharging, balancing the cells, and maintaining cell temperature within the safety limits during charging.
When building your system dont be tempted to mix & match aways use the batteries of the same make and size and where possible the same manufacturing batch so as to be sure that the BMS's are all the same model.
Efficiency: LiFePO4 batteries are more efficient than lead-acid batteries, meaning they require less energy to recharge after discharge. They also have a flat voltage curve, the charge voltage does not change much with different charge rates.
Float Voltage: Unlike lead-acid batteries, LiFePO4 batteries do not require a float charge They are either charging or not. If the charge controller cannot disable the float charge, set it to a low voltage (13.6V or less) to prevent actual charging.
Charging Profile of LiFePO4 Batteries
LiFePO4 batteries have a charging profile that is very easy to follow. The following points explain the process.
Charge Voltage: The charging voltage for a 12.8V LiFePO4 battery is taken from the cell voltage. A single cell voltage is multiplied by four to get the approximate battery voltage. For example, a single cell charge voltage is 3.2V so for a 12.8V system, it would be about 13.6V to 14.4V esh.
Charging Stages:LiFePO4 there are two main stages:
Constant Current Stage (CC): The battery is charged with a constant current until the voltage reaches the absorption level, of around 14.4V for a 12.8V battery. During this stage, the voltage gradually increases.
Constant Voltage Stage: Once the absorption voltage is reached, the voltage is held constant, and the current gradually decreases. The battery is considered fully charged when the current drops to about 5% to 10% of the battery’s amp-hour (Ah) rating.
Equalization: LiFePO4 batteries do not require equalization. If the charge controller has an equalization setting that cannot be disabled, set it to 14.6V or less so it functions as a normal absorption charge cycle.
High Voltage Protection: The BMS typically allows a maximum voltage of 14.8V to 15.0V before disconnecting the battery to prevent overcharging. There is no benefit to charging at higher voltages and doing so increases the risk of triggering the BMS protection and potential damage.
While LiFePO4 batteries are generally easier to manage and charge than lead-acid batteries, understanding their charging requirements and the role of the BMS is crucial for maintaining LFP battery health and longevity. Properly configuring the solar charge controller to align with these requirements ensures optimal performance and safety.
Absorption time:
There is a lot to be said for just setting the absorption voltage to 14.4V or 14.6V, and then stop charging once the battery reaches that voltage! In short, zero (or short) absorb time. At that point, the battery will be about 90% full. LiFePO4 batteries will be happier in the long run when they don’t stay at 100% SOC for too long, so this practice will extend your battery life. If you absolutely must have 100% SOC in your battery, absorb it will do! Officially, this is achieved when the charging current drops to 5% – 10% of the battery Ah value, i.e. 5-10 Amp for a 100Ah battery If you cannot stop absorbing the current, set the absorption time to about 2 hours and call Temperature compensation LiFePO4 Batteries do not require temperature compensation! Turn this off in the charge controller, otherwise, the charge voltage will be wildly turned off when it is very hot or cold. Check the voltage settings of the charge controller against actual voltage measured with a good quality DMM! Small changes in voltage can make a big difference during charging a lithium-ion battery! Change the charge settings accordingly!
Discharging an LFP Battery
Unlike lead acid batteries, the voltage of a lithium-ion battery remains very constant during discharge, making it difficult to guess the state of charge from the voltage alone. For a battery with a moderate load, the discharge curve seems LiFePO4 Discharge voltage vs. discharge voltage SOC LiFePO4 vs. SOC Most of the time during discharge, the battery voltage will be just around 13.2 volts. it was a really bad idea ™ to go below 20% SOC for a LiFePO4 battery. This has changed and the current LFP battery harvest will quite happily discharge down to 0% for many cycles. However, there is an advantage in pedaling less deep. It’s not just that going to 30% SOC will get you 1 / 3 cycles more than 0%, the battery will likely last more cycles than that. The hard numbers are, well, hard to find, but the cycle up to 50% SOC seems to show about 3 times the cycle life compared to .cycling 100%. Below is a table showing the battery voltage for a 12 Volt battery pack with respect to depth of discharge. Take these voltage values with a pinch of salt, the discharge curve is so flat that it is really difficult to determine SOC from voltage alone: small variations in load and accuracy of the voltmeter will negate the measurement.